Recently I have found these very interesting podcasts. David interviewed a few famous polyglots like Alex Rawlings, Robert Bigler, Moses McCormick, Luca Lampariello, Richard Simcott and others.
“The Polyglot Project Podcast”
http://www.davidmansaray.com/category/language-podcast
http://www.davidmansaray.com/category/language-podcast/page/2